Ethylene–norbornene copolymerization by rare-earth metal complexes and by carbon nanotube-supported metallocene catalysis (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Ethylene–norbornene copolymerization by rare-earth metal complexes and by carbon nanotube-supported metallocene catalysis (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/masy.200751416 (literal)

Alternative label

• I. Tritto, L. Boggioni, A. Ravasio, C. Zampa, J. Hitzbleck, J. Okuda, S. Bredeau, P. Dubois (2007)
  Ethylene–norbornene copolymerization by rare-earth metal complexes and by carbon nanotube-supported metallocene catalysis
  in Macromolecular symposia
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• I. Tritto, L. Boggioni, A. Ravasio, C. Zampa, J. Hitzbleck, J. Okuda, S. Bredeau, P. Dubois (literal)

Pagina inizio

• 114 (literal)

Pagina fine

• 121 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/masy.200751416/abstract (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 260 (literal)

Rivista

• Macromolecular symposia (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• I. Tritto, L. Boggioni, A. Ravasio, C. Zampa,Istituto per lo Studio delle Macromolecole (ISMAC) – CNR, Via Bassini 15, 20133 Milano J. Hitzbleck, J. Okuda, Institute of Inorganic Chemistry, RWTH Aachen University - Landoltweg 1 - D-52074 Aachen (Germany) S. Bredeau, P. Dubois, Services des Materiaux Polymeres et composites, Università de Mons-Hainaut, Place du Parc 20, Mons (Belgium (literal)

Titolo

• Ethylene–norbornene copolymerization by rare-earth metal complexes and by carbon nanotube-supported metallocene catalysis (literal)

Abstract

• E-N copolymerization with a number of half-sandwich rare-earth metal compounds [M(eta 5-C(5)Me(4)SiMe(2)R)(eta 1-CH(2)SiMe(3))(2)(L)] (M = Sc, Y, Lu) has been achieved. Mainly atactic alternating E-N copolymers are obtained with all catalytic systems. Interestingly, copolymers arising from [Sc(eta 5-C(5)Me(4)SiMe(2)C(6)F(5))(eta(1)-CH(2)SiMe(3))(2)(THF)]/[/ [Ph(3)C][B(C(6)F(5))(4)] possess narrower molar mass distributions than those from [SC(eta(5)-C(5)Me(4)SiMe(3))(eta(1)-CH(2)SiMe(3))(2)(THF)]/[Ph(3)C][B(C(6)F(5))(4)]. In addition, homogeneous surface coating of multi-walled carbon nanotubes is accomplished for the first time by in situ E-N copolymerization as catalyzed by rac-Et(Ind)(2)ZrCl(2)/MMAO-3A anchored onto the carbon nanotube surface. The copolymerization reaction allows for the destructuration of the native nanotube bundles. The relative quantity of E-N copolymer can be tuned up as well as the norbornene content in the formed copolymers and accordingly their glass transition temperature. By melt blending with an ethylene-vinyl-co-acetate copolymer (27 wt.-% vinyl acetate comonomer) matrix, high performance polyolefinic nanocomposites are obtained. (literal)

Prodotto di

• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR

• LAURA BOGGIONI (Persona)
• INCORONATA TRITTO (Persona)
• ANDREA RAVASIO (Persona)

Incoming links:

Autore CNR di

• LAURA BOGGIONI (Persona)
• INCORONATA TRITTO (Persona)
• ANDREA RAVASIO (Persona)

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecular symposia (Rivista)