http://www.cnr.it/ontology/cnr/individuo/prodotto/ID53337
Conformational Self-Recognition as the Origin of Dewetting in Bistable Molecular Surfaces (Articolo in rivista)
- Type
- Label
- Conformational Self-Recognition as the Origin of Dewetting in Bistable Molecular Surfaces (Articolo in rivista) (literal)
- Anno
- 2001-01-01T00:00:00+01:00 (literal)
- Alternative label
Cavallini, M 1.; Lazzaroni, R 2.; Zamboni, R. 3; Biscarini, F 4.; Timpel, D 5.; Zerbetto, F. 5; Clarkson, G. J. 7; Leigh, D. A. 8 (2001)
Conformational Self-Recognition as the Origin of Dewetting in Bistable Molecular Surfaces
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Cavallini, M 1.; Lazzaroni, R 2.; Zamboni, R. 3; Biscarini, F 4.; Timpel, D 5.; Zerbetto, F. 5; Clarkson, G. J. 7; Leigh, D. A. 8 (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1,2,3,4 - CNR-ISMN, Bologna, italy
5,6 - Dipartimento di Chimica , Universitá degli Studi di Bologna, Bologna, Italy
7,8 - Department of Chemistry, University of Warwick, Coventry , U.K (literal)
- Titolo
- Conformational Self-Recognition as the Origin of Dewetting in Bistable Molecular Surfaces (literal)
- Abstract
- A thin film formed by an amphiphilic catenane is shown to exhibit bistable behavior. The film is grown by self-assembly from two different solutions onto a mica surface. Self-recognition of the solute molecules by the first monolayer of the adsorbed molecules drives the switch between two co-conformations, characterized by different polar character, which are nearly degenerate once deposited on the surface. The phenomenon takes the form of a wetting/dewetting transition and propagates the intramolecular change to the mesoscopic scale.
(literal)
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