Ag/ZnO nanomaterials as high performance sensors for flammable and toxic gases (Articolo in rivista)

Type
Label
  • Ag/ZnO nanomaterials as high performance sensors for flammable and toxic gases (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Alternative label
  • Q. Simon, D. Barreca, A. Gasparotto, C. Maccato, E. Tondello, C. Sada, E. Comini, A. Devi, R.A. Fischer (2012)
    Ag/ZnO nanomaterials as high performance sensors for flammable and toxic gases
    in Nanotechnology (Bristol. Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Q. Simon, D. Barreca, A. Gasparotto, C. Maccato, E. Tondello, C. Sada, E. Comini, A. Devi, R.A. Fischer (literal)
Pagina inizio
  • 025502-1 (literal)
Pagina fine
  • 025502-7 (literal)
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  • Online supplementary data available from stacks.iop.org/Nano/23/025502/mmedia (literal)
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  • 23 (literal)
Rivista
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  • pubblicazione scientifica (literal)
Note
  • ISI Web of Science (WOS) (literal)
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  • 1,3,4,5: Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy 2: CNR-ISTM and INSTM, Department of Chemistry, Padova University, 35131 Padova, Italy 6: Department of Physics and CNISM, Padova University, 35131 Padova, Italy 7: CNR-IDASC, SENSOR Laboratory, Department of Chemistry and Physics, Brescia University, 25133 Brescia, Italy 8,9: Lehrstuhl fur Anorganische Chemie II, Ruhr-University Bochum, 44780 Bochum, Germany (literal)
Titolo
  • Ag/ZnO nanomaterials as high performance sensors for flammable and toxic gases (literal)
Abstract
  • Ag/ZnO nanocomposites supported on polycrystalline Al2O3 were synthesized by an unprecedented approach combining plasma enhanced chemical vapor deposition (PE-CVD) of ZnO matrices and the subsequent deposition of Ag nanoparticles (NPs) by radio frequency (RF) sputtering. The system structure, composition and morphology were investigated by glancing incidence x-ray diffraction (GIXRD), secondary ion mass spectrometry (SIMS), field emission scanning electron microscopy (FE-SEM) and energy dispersive x-ray spectroscopy (EDXS). A tailored dispersion and distribution of silver particles could be obtained under mild conditions by the sole variation of the sputtering time. Gas sensing properties toward flammable and toxic gases, both reducing (CH3CH2OH, CH3COCH3) and oxidizing (O3), were investigated in the temperature range 100–400 ºC. Beside the high sensitivity, the developed sensors exhibited a response proportional to Ag content, thanks to catalytic and electronic effects promoted by silver NPs. In addition, discrimination between oxidizing and reducing analytes was enabled by a suitable choice of the adopted working temperature. (literal)
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