Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/chem.200501619 (literal)

Alternative label

• Zaccheria F., Ravasio N., Psaro R., Fusi A. (2006)
  Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity
  in Chemistry (Weinh., Print); WILEY-V C H VERLAG GMBH, WEINHEIM (Germania)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Zaccheria F., Ravasio N., Psaro R., Fusi A. (literal)

Pagina inizio

• 6426 (literal)

Pagina fine

• 6431 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 24 (literal)

Rivista

• Chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Zaccheria, F.; Fusi, A.; Università di Milano (literal)

Titolo

• Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity (literal)

Abstract

• A method for the anaerobic oxidation of a wide series of alcohols including cyclohexanols and steroidal alcohols, has been set up. It relies on a transfer dehydrogenation reaction from the substrate alcohol to styrene catalyzed by a heterogeneous, reusable copper catalyst under very mild liquidphase experimental conditions (90 8C, N2) and shows unusual selectivity. Thus, the method is selective for the oxidation of secondary and allylic alcohols even in the presence of unprotected primary and benzylic alcohols. Electronic effects and the choice of the hydrogen acceptor account for the selectivity observed. (literal)

Editore

• WILEY-V C H VERLAG GMBH (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR

• MARIA NICOLETTA RAVASIO (Persona)
• RINALDO PSARO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR di

• RINALDO PSARO (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry (Rivista)

Editore di

• WILEY-V C H VERLAG GMBH (Editore)

Insieme di parole chiave di

• Keywords of "Synthetic Scope of Alcohol Transfer Dehydrogenation Catalyzed by Cu/Al2O3: A New Metallic Catalyst with Unusual Selectivity" (Insieme di parole chiave)