http://www.cnr.it/ontology/cnr/individuo/prodotto/ID42528
Steam reactivation of a spent sorbent for enhanced SO2 capture in FBC (Articolo in rivista)
- Type
- Label
- Steam reactivation of a spent sorbent for enhanced SO2 capture in FBC (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/aic.11026 (literal)
- Alternative label
Montagnaro F., Pallonetto F., Salatino P., Scala F. (2006)
Steam reactivation of a spent sorbent for enhanced SO2 capture in FBC
in AIChE journal
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Montagnaro F., Pallonetto F., Salatino P., Scala F. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto di Ricerche sulla Combustione IRC-CNR
Dipartimento di Ingegneria Chimica - Università Federico II Napoli
Facoltà di Scienze - Università Federico II Napoli (literal)
- Titolo
- Steam reactivation of a spent sorbent for enhanced SO2 capture in FBC (literal)
- Abstract
- The regeneration by steam hydration of the sulfur capture ability of spent sorbent
particles from Fluidized Bed Combustion (FBC) is addressed. The process is characterized
in terms of effectiveness of sorbent reactivation, hydration degree, particle sulfation
pattern, development of accessible porosity, and extent of particle attrition and
fragmentation. Steam reactivation experiments were carried out in a lab-scale atmospheric
FBC at 2508C for 10, 30, and 180 min with 0.05 MPa steam partial pressure.
The effectiveness of sorbent reactivation was assessed by reinjecting the reactivated
material into the FB reactor operated at 8508C under simulated desulfurization conditions
and following the degree of calcium conversion and the attrition rate along with
resulfation. The experimental results indicated that steam reactivation is effective in
renewing the SO2 uptake ability of the exhausted sorbent particles. The regeneration
mechanism based on the swelling upon hydration of the unreacted core, the generation
of fissures and cracks, and the consequent development of accessible porosity is confirmed
for the limestone under scrutiny. In addition to this, a remarkable result was
that steam hydration induces, for the sorbent under investigation, a pronounced sulfur
redistribution throughout the particle cross-section, which provides another pathway to
the enhancement of the sulfur capture ability of the reactivated sorbent. (literal)
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