CURING OF A RIGID-ROD EPOXY-RESIN WITH AN ALIPHATIC DIACID - AN EXAMPLE OF A LIGHTLY CROSS-LINKED LIQUID-CRYSTALLINE THERMOSET (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• CURING OF A RIGID-ROD EPOXY-RESIN WITH AN ALIPHATIC DIACID - AN EXAMPLE OF A LIGHTLY CROSS-LINKED LIQUID-CRYSTALLINE THERMOSET (Articolo in rivista) (literal)

Anno

• 1995-01-01T00:00:00+01:00 (literal)

Alternative label

• GIAMBERINI M, AMENDOLA E, CARFAGNA C (1995)
  CURING OF A RIGID-ROD EPOXY-RESIN WITH AN ALIPHATIC DIACID - AN EXAMPLE OF A LIGHTLY CROSS-LINKED LIQUID-CRYSTALLINE THERMOSET
  in Macromolecular rapid communications
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• GIAMBERINI M, AMENDOLA E, CARFAGNA C (literal)

Pagina inizio

• 97 (literal)

Pagina fine

• 105 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 16 (literal)

Rivista

• Macromolecular rapid communications (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• UNIV NAPLES FEDERICO II, DEPT MAT & PROD ENGN, I-80125 NAPLES, ITALY CNR ITMC, I-80125 NAPLES, ITALY (literal)

Titolo

• CURING OF A RIGID-ROD EPOXY-RESIN WITH AN ALIPHATIC DIACID - AN EXAMPLE OF A LIGHTLY CROSS-LINKED LIQUID-CRYSTALLINE THERMOSET (literal)

Abstract

• By reacting a rigid rod epoxy terminated molecule (p-bis(2,3-epoxypropoxy)-alpha-methylstilbene) with an aliphatic carboxylic acid (decanedioic acid), a lightly crosslinked liquid crystalline network is obtained. This network exhibits a smectic-like phase. While the mesophasic structure resulted ''frozen'' by the crosslinks in the case of highly crosslinked liquid crystalline epoxy resins, in this case a reversible transition from the liquid crystalline to the isotropic phase is observed. Moreover, while curing the same rigid rod epoxy molecule with amines resulted in a thermoset with a nematic structure, in this case a more ordered mesophase can be obtained. Preliminary results show that it is possible to orient macroscopically the mesogenic chains by stretching thin films above the glass transition temperature (T-g) and then quickly cooling down to the glassy stale. This makes this material very attractive in the field of optical applications. (literal)

Prodotto di

• Istituto per i materiali compositi e biomedici (IMCB) (Istituto)

Autore CNR

• MARTA GIAMBERINI (Persona)
• EUGENIO AMENDOLA (Unità di personale interno)

Incoming links:

Prodotto

• Istituto per i materiali compositi e biomedici (IMCB) (Istituto)

Autore CNR di

• EUGENIO AMENDOLA (Unità di personale interno)
• MARTA GIAMBERINI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecular rapid communications (Rivista)