@prefix prodottidellaricerca: . @prefix istituto: . @prefix prodotto: . istituto:CDS070 prodottidellaricerca:prodotto prodotto:ID298796 . @prefix pubblicazioni: . @prefix unitaDiPersonaleInterno: . unitaDiPersonaleInterno:MATRICOLA8383 pubblicazioni:autoreCNRDi prodotto:ID298796 . @prefix rdf: . @prefix retescientifica: . prodotto:ID298796 rdf:type retescientifica:ProdottoDellaRicerca , prodotto:TIPO1301 . @prefix rdfs: . prodotto:ID298796 rdfs:label "Lumped kinetics of reactions of volatiles and tar from plastic wastes (Contributo in atti di convegno)"@en . @prefix xsd: . prodotto:ID298796 pubblicazioni:anno "2014-01-01T00:00:00+01:00"^^xsd:gYear . @prefix skos: . prodotto:ID298796 skos:altLabel "
Teresa TUCCILLO, Osvalda SENNECA (2014)
Lumped kinetics of reactions of volatiles and tar from plastic wastes
in Joint meeting of the Italian and french Sections of the Combustion Institute, Pisa, 2014
"^^rdf:HTML ; pubblicazioni:autori "Teresa TUCCILLO, Osvalda SENNECA"^^xsd:string ; pubblicazioni:affiliazioni "Universit\u00E0 degli Studi di Napoli Federico II, DICMAPI, Piazzale Tecchio 80, Napoli, Italy, teresa.tuccillo@unina,it\nIstituto di Ricerche sulla Combustione, Piazzale Tecchio 80, Napoli, Italy, senneca@irc.cnr.it"^^xsd:string ; pubblicazioni:titolo "Lumped kinetics of reactions of volatiles and tar from plastic wastes"^^xsd:string ; prodottidellaricerca:abstract "The goal of this paper was to set up a semi-detailed kinetic scheme for the fate of volatiles and tar produced from pyrolysis of plastic wastes. The scheme must be simple enough to be implemented in codes for the simulation of full scale reactors of pyrolysis, combustion and gasification. According to our scheme, under oxygen rich conditions volatiles and tar are readily oxidized (reactions 3 and 4), but under fuel rich conditions volatiles can undergo further transformations. We supposed that primary tar is mostly formed by long aliphatic chains. We chose n-hexadecane as representative of such young tar. Secondary reactions result in progressive aromatization and loss of hydrogen. We assumed naphthalene as representative of this class of intermediate products (reaction 1). Further reactions eventually lead to large PAHs and soot formation (reaction 2). Rate expressions for the lumped reaction scheme proposed have been obtained from regression of results of computational Chemkin experiments, based on the reaction network of Ranzi and coworkers (198 species and 6307 reactions)." ; prodottidellaricerca:prodottoDi istituto:CDS070 ; pubblicazioni:autoreCNR unitaDiPersonaleInterno:MATRICOLA8383 .