The Cl(2p) photoelectron spectra of the HCl and DCl molecules: the effects of the molecular field (Articolo in rivista)

Type
Label
  • The Cl(2p) photoelectron spectra of the HCl and DCl molecules: the effects of the molecular field (Articolo in rivista) (literal)
Anno
  • 2000-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1088/0953-4075/33/5/102 (literal)
Alternative label
  • Mika Kivilompolo, Antti Kivimäki, Marko Jurvansuu, Helena Aksela, Seppo Aksela, Reinhold F Fink (2000)
    The Cl(2p) photoelectron spectra of the HCl and DCl molecules: the effects of the molecular field
    in Journal of physics. B, Atomic molecular and optical physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Mika Kivilompolo, Antti Kivimäki, Marko Jurvansuu, Helena Aksela, Seppo Aksela, Reinhold F Fink (literal)
Pagina inizio
  • L157 (literal)
Pagina fine
  • L164 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 33 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Department of Physical Sciences, PO Box 3000, FIN-90014, University of Oulu, Finland Theoretical Chemistry, University of Bochum, D-44780 Bochum, German (literal)
Titolo
  • The Cl(2p) photoelectron spectra of the HCl and DCl molecules: the effects of the molecular field (literal)
Abstract
  • The Cl(2p) photoelectron spectra of HCl and DCl have been measured with high resolution. Careful data analysis with a least-squares fitting method enabled us to determine the spectroscopic parameters for the three spin-orbit and molecular field split components of the Cl(2p)-1 states. The experimental results were compared with ab initio calculations. The values of 84±9 meV, 71±13 meV, and 103±10 meV for the lifetime line widths of 2 Pi 1/2 , 2 Sigma 1/2 + , and 2 Pi 3/2 states were extracted from the experiment. An anomalous photoionization cross section ratio (60%) between the 2 Sigma 1/2 + and 2 Pi 3/2 states was observed. (literal)
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