A new case of Polymorphism in Platinum(II) Complexes: [ptbr2(2, 9-dimethyl-1, 10-phenanthroline)] (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A new case of Polymorphism in Platinum(II) Complexes: [ptbr2(2, 9-dimethyl-1, 10-phenanthroline)] (Articolo in rivista) (literal)

Anno

• 2002-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1524/zkri.217.9.492.22884 (literal)

Alternative label

• Capitelli F., Margiotta N., Moliterni A.G.G., Natile G. (2002)
  A new case of Polymorphism in Platinum(II) Complexes: [ptbr2(2, 9-dimethyl-1, 10-phenanthroline)]
  in Zeitschrift für Kristallographie
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Capitelli F., Margiotta N., Moliterni A.G.G., Natile G. (literal)

Pagina inizio

• 492 (literal)

Pagina fine

• 496 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 217 (literal)

Rivista

• Zeitschrift für Kristallographie (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Cristallografia, 70100 Bari, Italy Dipartimento Farmaco-Chimico, 70100 Bari, Italy (literal)

Titolo

• A new case of Polymorphism in Platinum(II) Complexes: [ptbr2(2, 9-dimethyl-1, 10-phenanthroline)] (literal)

Abstract

• A novel case of polymorphism in platinum(II) complexes is reported. Single crystals of [PtBr2(2,9-dimethyl-1,10-phenanthroline)] were obtained at room temperature from a dilute dichloromethane/pentane (1:3, v/v) solution of the title compound in the presence of guanosine. The space group resulted to be Pbca [a = 20.4024(3), b = 20.3638(3), and c = 13.9522(2) Å, V = 5796.7(1) Å3, Z = 8]. Crystals of the same compound, obtained in slightly different conditions, had already been investigated by X-ray diffraction and found to have P21/n space group, [a = 12.155(4), b = 7.933(2), and c = 14.522(2) Å, ? = 93.74(2)°, V = 1397.3(6) Å3, Z = 4]. Comparison of the two polymorphous forms reveals huge differences in the crystal packing and the important role of the stacking interactions between phenanthroline ligands. (literal)

Prodotto di

• Istituto di cristallografia (IC) (Istituto)

Autore CNR

• ANNA MOLITERNI (Unità di personale interno)
• FRANCESCO CAPITELLI (Persona)

Incoming links:

Prodotto

• Istituto di cristallografia (IC) (Istituto)

Autore CNR di

• FRANCESCO CAPITELLI (Persona)
• ANNA MOLITERNI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Zeitschrift für Kristallographie (Rivista)