@prefix prodottidellaricerca: . @prefix istituto: . @prefix prodotto: . istituto:CDS064 prodottidellaricerca:prodotto prodotto:ID40887 . @prefix rdf: . @prefix retescientifica: . prodotto:ID40887 rdf:type retescientifica:ProdottoDellaRicerca , prodotto:TIPO1101 . @prefix rdfs: . prodotto:ID40887 rdfs:label "Determination of the structure of the lipid A fraction from the lipopolysaccharide of Pseudomonas cichorii by means of NMR and MALDI-TOF mass spectrometry (Articolo in rivista)"@en . @prefix xsd: . @prefix pubblicazioni: . prodotto:ID40887 pubblicazioni:anno "2002-01-01T00:00:00+01:00"^^xsd:gYear . @prefix skos: . prodotto:ID40887 skos:altLabel "
Molinaro A., Silipo A., Lanzetta R., Parrilli M., Malvagna P., Evidente A., Surico G. (2002)
Determination of the structure of the lipid A fraction from the lipopolysaccharide of Pseudomonas cichorii by means of NMR and MALDI-TOF mass spectrometry
in European journal of organic chemistry (Print)
"^^rdf:HTML ; pubblicazioni:autori "Molinaro A., Silipo A., Lanzetta R., Parrilli M., Malvagna P., Evidente A., Surico G."^^xsd:string ; pubblicazioni:paginaInizio "3119"^^xsd:string ; pubblicazioni:paginaFine "3125"^^xsd:string ; pubblicazioni:numeroVolume "18"^^xsd:string . @prefix ns9: . prodotto:ID40887 pubblicazioni:rivista ns9:ID176607 ; skos:note "ISI Web of Science (WOS)"^^xsd:string ; pubblicazioni:titolo "Determination of the structure of the lipid A fraction from the lipopolysaccharide of Pseudomonas cichorii by means of NMR and MALDI-TOF mass spectrometry"^^xsd:string ; prodottidellaricerca:abstract "The chemical structure of lipid A from the lipopolysaccharide of the plant-\nassociated bacterium Pseudomonas cichorii, was elucidated by compositional \nanalysis and spectroscopic methods (MALDI-TOF and 2D NMR). The lipid A \nfraction showed remarkable heterogeneity with respect to the fatty acid \nand phosphate composition. The major species are hexaacylated and \npentaacylated lipid A, bearing the (R)-3-hydroxydodecanoic acid [C12:0 \n(3OH)] in amide linkage and an (R)-3-hydroxydecanoic [C10:0 (3OH)] in \nester linkage while the secondary fatty acids are present as C12:0 and \nC12:0 (2-OH). A nonstoichiometric phosphate substitution at position C-4' \nof the distal GlcN was detected. Interestingly, the pentaacyl lipid A is \nlacking a primary fatty acid, namely the C10:0 (3-OH) at position C-3'. A \npotential biological meaning of this peculiar lipid A is also suggested." ; prodottidellaricerca:prodottoDi istituto:CDS064 . ns9:ID176607 pubblicazioni:rivistaDi prodotto:ID40887 .