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Istituto sull'inquinamento atmosferico

Torna all'elenco Contributi in rivista anno 2013

Contributo in rivista

Tipo: Articolo in rivista

Titolo: Determination of 5-ethylidene-2-norbornene in industrial emission.

Anno di pubblicazione: 2013

Formato: Elettronico

Autori: Camerini, F., Guerriero, E., Mosca, S., Rotatori, M.

Affiliazioni autori: CNR-IIA

Autori CNR:


Lingua: inglese

Abstract: A method to measure the emissive concentration of 5-ethylidene-2-norbornene (ENB), a reactive compound used in industrial synthesis of terpolymers, has been developed. The starting points for the development of the presented method are European and Italian reference methods for the quantification of nonreactive volatile organic compounds in industrial emission. In this study, sampling conditions and desorption solvent have been optimized in laboratory and the method was applied in an industrial plant. The laboratory tests showed a good recovery (88-95 %). The concentrations of ENB in industrial emission obtained with the developed method were compared with an online gas chromatography-flame ionization results (R2 >0.97). In addition, several manual measurements were performed in parallel, and the resulting %RSD repeatability was <9 %. The developed method provides a discontinuous technique to measure reactive volatile organic compounds using easy-to-use instruments and assures a very good accuracy and precision even with high-humidity gas flows. The method could be extended to other reactive compounds of the same class

Lingua abstract: inglese

Pagine da: 4881

Pagine a: 4885

Pagine totali: 5


Environmental science and pollution research international Springer
Paese di pubblicazione: Germania
Lingua: inglese
ISSN: 0944-1344

Numero volume: 20

DOI: 10.1007/s11356-012-1453-4

Referee: Sė: Internazionale

Stato della pubblicazione: Published version

Indicizzato da:

  • Scopus [2-s2.0-84879684718]
  • ISI Web of Science (WOS) [000321126700050]

Parole chiave:

  • Industrial emissions . Polymerization . Volatile organic compound . Reactive . Charcoal . para-tertButylcatechol . Ethylidene . Norbornene

Strutture CNR:


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